Yayın:
Synthesis and Crystal Structure of 3-Amino-1-(5-Chloro-2-Hydroxyphenyl)Imidazolidine-2,4-Dione

Basit Görünüm
dc.contributor.authorAydin, Abdullah
dc.contributor.authorOnkol, Tijen
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorBüyükgüngör, Orhan
dc.contributor.authorSahin, M. Fethi
dc.date.accessioned2026-01-02T22:55:11Z
dc.date.issued2013-01-01
dc.description.abstractThe present study describes the synthesis, spectral data, and single crystal X-ray structural analysis of 3-amino-1-(5-chloro-2-hydroxyphenyl)imidazolidine-2,4-dione. X-Ray analysis revealed that the title compound did not have the anticipated structure, but had that of a different substance. This unexpected conformation generated the interest in studying the synthesis of this compound. The inspected compound, 3-amino-1-(5-chloro-2-hydroxyphenyl)imidazolidine-2,4-dione, is a pharmaceutical intermediate and is nonplanar. Its benzene and five-membered rings have a dihedral angle of 53.95(7)°. The conformation is stabilized by intermolecular O‒H … O, O‒H … N, and N‒H … O interactions and a weak C‒H … π interaction.
dc.description.urihttps://doi.org/10.1080/15421406.2012.707593
dc.description.urihttps://dx.doi.org/10.1080/15421406.2012.707593
dc.description.urihttps://avesis.gazi.edu.tr/publication/details/af9be0e9-030a-4083-bb1c-d80ce0d61177/oai
dc.description.urihttps://avesis.erciyes.edu.tr/publication/details/af9be0e9-030a-4083-bb1c-d80ce0d61177/oai
dc.description.urihttps://hdl.handle.net/20.500.12712/16143
dc.identifier.doi10.1080/15421406.2012.707593
dc.identifier.eissn1563-5287
dc.identifier.endpage127
dc.identifier.issn1542-1406
dc.identifier.openairedoi_dedup___::34b08e9feabfa54aa04c3e4f8be3e55d
dc.identifier.orcid0000-0003-2805-9314
dc.identifier.scopus2-s2.0-84873353098
dc.identifier.startpage119
dc.identifier.urihttps://hdl.handle.net/20.500.12597/35663
dc.identifier.volume570
dc.identifier.wos000316060900014
dc.language.isoeng
dc.publisherInforma UK Limited
dc.relation.ispartofMolecular Crystals and Liquid Crystals
dc.rightsCLOSED
dc.subjectX-ray
dc.subjectsynthesis
dc.subjectstructure
dc.subjectdione
dc.subjectamino
dc.titleSynthesis and Crystal Structure of 3-Amino-1-(5-Chloro-2-Hydroxyphenyl)Imidazolidine-2,4-Dione
dc.typeArticle
dspace.entity.typePublication
local.api.response{"authors":[{"fullName":"Aydin, Abdullah","name":"Abdullah","surname":"Aydin","rank":1,"pid":{"id":{"scheme":"orcid","value":"0000-0003-2805-9314"},"provenance":null}},{"fullName":"Onkol, Tijen","name":"Tijen","surname":"Onkol","rank":2,"pid":null},{"fullName":"Akkurt, Mehmet","name":"Mehmet","surname":"Akkurt","rank":3,"pid":null},{"fullName":"Büyükgüngör, Orhan","name":"Orhan","surname":"Büyükgüngör","rank":4,"pid":null},{"fullName":"Sahin, M. Fethi","name":"M. Fethi","surname":"Sahin","rank":5,"pid":null}],"openAccessColor":null,"publiclyFunded":false,"type":"publication","language":{"code":"eng","label":"English"},"countries":null,"subjects":[{"subject":{"scheme":"keyword","value":"X-ray"},"provenance":null},{"subject":{"scheme":"keyword","value":"synthesis"},"provenance":null},{"subject":{"scheme":"keyword","value":"2"},"provenance":null},{"subject":{"scheme":"keyword","value":"structure"},"provenance":null},{"subject":{"scheme":"keyword","value":"4-dione"},"provenance":null},{"subject":{"scheme":"FOS","value":"01 natural sciences"},"provenance":null},{"subject":{"scheme":"keyword","value":"3-amino"},"provenance":null},{"subject":{"scheme":"FOS","value":"0104 chemical sciences"},"provenance":null}],"mainTitle":"Synthesis and Crystal Structure of 3-Amino-1-(5-Chloro-2-Hydroxyphenyl)Imidazolidine-2,4-Dione","subTitle":null,"descriptions":["The present study describes the synthesis, spectral data, and single crystal X-ray structural analysis of 3-amino-1-(5-chloro-2-hydroxyphenyl)imidazolidine-2,4-dione. X-Ray analysis revealed that the title compound did not have the anticipated structure, but had that of a different substance. This unexpected conformation generated the interest in studying the synthesis of this compound. The inspected compound, 3-amino-1-(5-chloro-2-hydroxyphenyl)imidazolidine-2,4-dione, is a pharmaceutical intermediate and is nonplanar. Its benzene and five-membered rings have a dihedral angle of 53.95(7)°. The conformation is stabilized by intermolecular O‒H … O, O‒H … N, and N‒H … O interactions and a weak C‒H … π interaction."],"publicationDate":"2013-01-01","publisher":"Informa UK Limited","embargoEndDate":null,"sources":["Crossref"],"formats":null,"contributors":["Ondokuz Mayıs Üniversitesi"],"coverages":null,"bestAccessRight":{"code":"c_14cb","label":"CLOSED","scheme":"http://vocabularies.coar-repositories.org/documentation/access_rights/"},"container":{"name":"Molecular Crystals and Liquid Crystals","issnPrinted":"1542-1406","issnOnline":"1563-5287","issnLinking":null,"ep":"127","iss":null,"sp":"119","vol":"570","edition":null,"conferencePlace":null,"conferenceDate":null},"documentationUrls":null,"codeRepositoryUrl":null,"programmingLanguage":null,"contactPeople":null,"contactGroups":null,"tools":null,"size":null,"version":null,"geoLocations":null,"id":"doi_dedup___::34b08e9feabfa54aa04c3e4f8be3e55d","originalIds":["10.1080/15421406.2012.707593","50|doiboost____|34b08e9feabfa54aa04c3e4f8be3e55d","2072109771","af9be0e9-030a-4083-bb1c-d80ce0d61177","50|od_____10046::e033df01c9c8a91f562bd42550be0e3c","50|od______9447::e033df01c9c8a91f562bd42550be0e3c","50|od______9773::af85b3068be196770f986d3cc15789a7","oai:acikerisim.omu.edu.tr:20.500.12712/16143"],"pids":[{"scheme":"doi","value":"10.1080/15421406.2012.707593"},{"scheme":"handle","value":"20.500.12712/16143"}],"dateOfCollection":null,"lastUpdateTimeStamp":null,"indicators":{"citationImpact":{"citationCount":0,"influence":2.5349236e-9,"popularity":6.0129673e-10,"impulse":0,"citationClass":"C5","influenceClass":"C5","impulseClass":"C5","popularityClass":"C5"},"usageCounts":{"downloads":0,"views":9}},"instances":[{"pids":[{"scheme":"doi","value":"10.1080/15421406.2012.707593"}],"type":"Article","urls":["https://doi.org/10.1080/15421406.2012.707593"],"publicationDate":"2013-01-01","refereed":"peerReviewed"},{"alternateIdentifiers":[{"scheme":"mag_id","value":"2072109771"},{"scheme":"doi","value":"10.1080/15421406.2012.707593"}],"type":"Article","urls":["https://dx.doi.org/10.1080/15421406.2012.707593"],"refereed":"nonPeerReviewed"},{"alternateIdentifiers":[{"scheme":"doi","value":"10.1080/15421406.2012.707593"}],"type":"Article","urls":["https://avesis.gazi.edu.tr/publication/details/af9be0e9-030a-4083-bb1c-d80ce0d61177/oai"],"publicationDate":"2013-01-01","refereed":"nonPeerReviewed"},{"alternateIdentifiers":[{"scheme":"doi","value":"10.1080/15421406.2012.707593"}],"type":"Article","urls":["https://avesis.erciyes.edu.tr/publication/details/af9be0e9-030a-4083-bb1c-d80ce0d61177/oai"],"publicationDate":"2013-01-01","refereed":"nonPeerReviewed"},{"pids":[{"scheme":"handle","value":"20.500.12712/16143"}],"alternateIdentifiers":[{"scheme":"doi","value":"10.1080/15421406.2012.707593"}],"type":"Article","urls":["https://doi.org/10.1080/15421406.2012.707593","https://hdl.handle.net/20.500.12712/16143"],"publicationDate":"2020-06-21","refereed":"nonPeerReviewed"},{"alternateIdentifiers":[{"scheme":"mag_id","value":"2072109771"},{"scheme":"doi","value":"10.1080/15421406.2012.707593"}],"type":"Article","urls":["https://dx.doi.org/10.1080/15421406.2012.707593"],"refereed":"nonPeerReviewed"}],"isGreen":false,"isInDiamondJournal":false}
local.import.sourceOpenAire
local.indexed.atWOS
local.indexed.atScopus

Dosyalar

Koleksiyonlar

Publications