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A combined electrochemical and theoretical study into the effect of 2-((thiazole-2-ylimino)methyl)phenol as a corrosion inhibitor for mild steel in a highly acidic environment

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dc.contributor.authorYilmaz, Nurdane
dc.contributor.authorFitoz, Alper
dc.contributor.authorErgun, ÿmit
dc.contributor.authorEmregül, Kaan C.
dc.date.accessioned2026-01-02T23:47:24Z
dc.date.issued2016-10-01
dc.description.abstractAbstract 2-((Thiazole-2-ylimino)methyl)phenol (THYMP) was studied as a corrosion inhibitor for the protection of mild steel in 2 M HCl solution by means of weight loss, polarization, electrochemical impedance spectroscopy and scanning electron microscopy. The potential of zero charge (E pzc ), was also determined for evaluation of the adsorption mechanism. Quantum chemical parameters such as highest occupied molecular orbital energy (E HOMO ), lowest unoccupied molecular orbital energy (E LUMO ), energy gap (οE), dipole moment (μ) etc. were calculated using density functional theory (DFT) at B3LYP/6-31G(d,p) level. Theoretical and experimental results were in fairly good agreement.
dc.description.urihttps://doi.org/10.1016/j.corsci.2016.05.002
dc.description.urihttps://dx.doi.org/10.1016/j.corsci.2016.05.002
dc.description.urihttps://hdl.handle.net/20.500.12684/2314
dc.identifier.doi10.1016/j.corsci.2016.05.002
dc.identifier.endpage120
dc.identifier.issn0010-938X
dc.identifier.openairedoi_dedup___::aed19f6cf873a395daea0c5fb1ac1e4e
dc.identifier.orcid0000-0003-1760-8066
dc.identifier.orcid0000-0001-7714-9987
dc.identifier.orcid0000-0002-2991-9702
dc.identifier.scopus2-s2.0-84975143293
dc.identifier.startpage110
dc.identifier.urihttps://hdl.handle.net/20.500.12597/36263
dc.identifier.volume111
dc.identifier.wos000382794000010
dc.language.isoeng
dc.publisherElsevier BV
dc.relation.ispartofCorrosion Science
dc.rightsOPEN
dc.subjectMild steel
dc.subjectEIS
dc.subjectCorrosion inhibitor
dc.subjectPolarization
dc.subjectSEM
dc.subjectDFT
dc.titleA combined electrochemical and theoretical study into the effect of 2-((thiazole-2-ylimino)methyl)phenol as a corrosion inhibitor for mild steel in a highly acidic environment
dc.typeArticle
dspace.entity.typePublication
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