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Novel Disubstituted Calix[4]arenes Containing Chromogenic Groups on the Lower Rim: Synthesis, Structural Identification, and Absorption Properties

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dc.contributor.authorŞener, Nesrin
dc.contributor.authorErişkin, Selinay
dc.contributor.authorGür, Mahmut
dc.contributor.authorŞener, İzzet
dc.date.accessioned2026-01-03T10:29:01Z
dc.date.issued2018-02-12
dc.description.abstract5,11,17,23‐Tetra‐tert‐butyl‐25,26,27,28‐tetrahydroxycalix[4]arene and 25,26,27,28‐tetrahydroxycalix[4]arene were synthesized based on previous literature. Firstly, several azo dyes were synthesized, and then, these dyestuffs were chlorinated through reaction with thionyl chloride. Secondly, the azo compounds bonded with methylene chloride and reacted with 25,26,27,28‐tetrahydroxycalix[4]arene, and then, six novel disazocalix[4]arene derivatives 4(a–f) were achieved. Their structures were characterized as Fourier transform infrared, 1H‐NMR, and elemental analysis. In this study, we investigated the solvatochromic properties of the compounds and the acid–base effect on their ultraviolet–visible absorption by using six solvents.
dc.description.urihttps://doi.org/10.1002/jhet.3129
dc.description.urihttps://dx.doi.org/10.1002/jhet.3129
dc.description.urihttps://hdl.handle.net/11499/10811
dc.description.urihttp://acikerisim.pau.edu.tr:8080/xmlui/handle/11499/10811
dc.description.urihttps://aperta.ulakbim.gov.tr/record/35683
dc.description.urihttps://doi.org/https://doi.org/10.1002/jhet.3129
dc.identifier.doi10.1002/jhet.3129
dc.identifier.eissn1943-5193
dc.identifier.endpage994
dc.identifier.issn0022-152X
dc.identifier.openairedoi_dedup___::7938778100a2dd5403c11bc59d5ba2a7
dc.identifier.orcid0000-0001-5370-6048
dc.identifier.orcid0000-0001-9942-6324
dc.identifier.orcid0000-0003-0540-7523
dc.identifier.scopus2-s2.0-85041852227
dc.identifier.startpage988
dc.identifier.urihttps://hdl.handle.net/20.500.12597/36747
dc.identifier.volume55
dc.identifier.wos000430179800027
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofJournal of Heterocyclic Chemistry
dc.rightsOPEN
dc.subjectsynthesis
dc.subjectdimethyl sulfoxide
dc.subjectproton nuclear magnetic resonance
dc.subjectArticle
dc.subjecttautomer
dc.subjectazo dye
dc.subjectheterocyclic amine
dc.subjectchemical bond
dc.subjectinfrared spectroscopy
dc.subjectmethanol
dc.subjectchlorination
dc.subjectchloroform
dc.subjectpH
dc.subjectelemental analysis
dc.subjectdichloromethane
dc.subjectn,n dimethylformamide
dc.subjectunclassified drug
dc.subjectacetonitrile
dc.subjectchromogenic substrate
dc.subjectacetic acid
dc.subjectultraviolet spectrophotometry
dc.subjectchemical structure
dc.subjectcalixarene
dc.subjectdisazocalix[4]arene derivative
dc.subject.sdg3. Good health
dc.titleNovel Disubstituted Calix[4]arenes Containing Chromogenic Groups on the Lower Rim: Synthesis, Structural Identification, and Absorption Properties
dc.typeArticle
dspace.entity.typePublication
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