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A Degradation Kinetic Study on Pyrolysis of Three Biomass Samples and Co-pyrolysis of Hazelnut Shell and Ultra-high Molecular Weight Polyethylene Blends Using a Silver Indicator

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dc.contributor.authorAydinli, B.
dc.contributor.authorCaglar, A.
dc.date.accessioned2026-01-05T23:26:45Z
dc.date.issued2013-05-15
dc.description.abstractA kinetic study was proposed in pyrolysis process supplementary to thermo-gravimetric analysis. Three different biomasses, hazelnut shell, olive residue, and tea waste, and hazelnut shell and ultra-high molecular weight polyethylene mixture were analyzed kinetically in a batch-type tubular pyrolysis reactor. Reaction times were measured with the changing color of silver indicator, which was attached to the terminal of pyrolysis set up at various specified temperatures between 623 and 923 K. The Arrhenius plots were obtained and the activation energies (Ea ) of reaction values were calculated from the slope of linear curves. For pure biomass, two linear degradation zones were detected possibly belonging to cellulose and hemicellulose. In the case of hazelnut shell and ultra-high molecular weight polyethylene mixtures, linearity of Arrhenius plots were grasped with the modification of the pre-exponential factor of the basic Arrhenius equation. This type of kinetic method directly involves the basic paramete...
dc.description.urihttps://doi.org/10.1080/15567036.2010.512909
dc.description.urihttps://dx.doi.org/10.1080/15567036.2010.512909
dc.identifier.doi10.1080/15567036.2010.512909
dc.identifier.eissn1556-7230
dc.identifier.endpage908
dc.identifier.issn1556-7036
dc.identifier.openairedoi_dedup___::cacf690bc4555c15487f493a7ce8d159
dc.identifier.scopus2-s2.0-84876140833
dc.identifier.startpage900
dc.identifier.urihttps://hdl.handle.net/20.500.12597/43798
dc.identifier.volume35
dc.identifier.wos000317293000002
dc.language.isoeng
dc.publisherInforma UK Limited
dc.relation.ispartofEnergy Sources, Part A: Recovery, Utilization, and Environmental Effects
dc.subject.sdg7. Clean energy
dc.titleA Degradation Kinetic Study on Pyrolysis of Three Biomass Samples and Co-pyrolysis of Hazelnut Shell and Ultra-high Molecular Weight Polyethylene Blends Using a Silver Indicator
dc.typeArticle
dspace.entity.typePublication
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