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Synthesis, Characterization, and Fluorescence Studies of Novel Heterocyclic Azo Dyes Derived from Benzothiazole

dc.contributor.authorŞener, Nesrin
dc.contributor.authorErişkin, Selinay
dc.contributor.authorŞahin, Çiğdem
dc.contributor.authorYılmaz, Mehmet
dc.contributor.authorŞener, İzzet
dc.date.accessioned2026-01-03T10:09:25Z
dc.date.issued2017-08-31
dc.description.abstractTen novel fluorescent azo disperse dyes2a–e(open forms) and3a–e(closed forms) were obtained by the coupling reaction of carbocyclic amine based diazonium chloride with compounds2and3. The synthesized dyes were characterized by elemental analysis, high‐resolution mass spectrometry, Fourier transform infrared, and NMR spectral techniques. Moreover, we investigated the substituent effect and solvatochromic properties of the dyes on absorption and fluorescence spectra. At the same time, the absorption and emission spectral data of the closed form dyes3a–ewere compared with the open form dyes2a–edue to more planarity of the closed form dyes that lead to the extension of the π–electron conjugation.
dc.description.urihttps://doi.org/10.1002/jhet.2974
dc.description.urihttps://dx.doi.org/10.1002/jhet.2974
dc.description.urihttps://avesis.kocaeli.edu.tr/publication/details/2f96dc87-4835-4199-ac06-de6de883638e/oai
dc.description.urihttps://hdl.handle.net/11499/8879
dc.description.urihttp://acikerisim.pau.edu.tr:8080/xmlui/handle/11499/8879
dc.description.urihttps://doi.org/https://doi.org/10.1002/jhet.2974
dc.identifier.doi10.1002/jhet.2974
dc.identifier.eissn1943-5193
dc.identifier.endpage3518
dc.identifier.issn0022-152X
dc.identifier.openairedoi_dedup___::de3ec165786ba43a9c1a4b9844664ca3
dc.identifier.orcid0000-0001-5370-6048
dc.identifier.orcid0000-0003-0540-7523
dc.identifier.scopus2-s2.0-85028642451
dc.identifier.startpage3510
dc.identifier.urihttps://hdl.handle.net/20.500.12597/36522
dc.identifier.volume54
dc.identifier.wos000422654000063
dc.language.isoeng
dc.publisherWiley
dc.relation.ispartofJournal of Heterocyclic Chemistry
dc.rightsOPEN
dc.subjectabsorption spectroscopy
dc.subjectethyl 3 (1,3 benzothiazol 2 ylamino) 3 hydroxy 2 (4' chlorphenylazo)acrylate
dc.subjectsynthesis
dc.subjectethyl 3 (1,3 benzothiazol 2 ylamino) 3 hydroxy 2 (4' methylphenylazo)acrylate
dc.subjectethyl 3 (1,3 benzothiazol 2 ylamino) 3 hydroxy 2(phenylazo)acrylate
dc.subjecthydroxy 3 (4' chlorphenylazo) 4h pyrimido[2,1 b][1,3]benzothiazol 4 one
dc.subjectArticle
dc.subjecthydroxy 3 (phenylazo) 4h pyrimido[2,1 b][1,3]benzothiazol 4 one
dc.subjectazo dye
dc.subjecthydroxy 3 (4' methylphenylazo) 4h pyrimido[2,1 b][1,3]benzothiazol 4 one
dc.subjectinfrared spectroscopy
dc.subjectmass spectrometry
dc.subjectnuclear magnetic resonance spectroscopy
dc.subjectheterocyclic compound
dc.subjectelemental analysis
dc.subjecthydroxy 3 (4' nitrophenylazo) 4h pyrimido[2,1 b][1,3]benzothiazol 4 one
dc.subjectethyl 3 (1,3 benzothiazol 2 ylamino) 3 hydroxy 2 (4' methoxyphenylazo)acrylate
dc.subjecthydroxy 3 (4' methoxyphenylazo) 4h pyrimido[2,1 b][1,3]benzothiazol 4 one
dc.subjectbenzothiazole
dc.subjectfluorescence spectroscopy
dc.subjectunclassified drug
dc.subjectultraviolet spectrophotometry
dc.subjectethyl 3 (1,3 benzothiazol 2 ylamino) 3 hydroxy 2 (4' nitrophenylazo)acrylate
dc.subject.sdg16. Peace & justice
dc.subject.sdg3. Good health
dc.titleSynthesis, Characterization, and Fluorescence Studies of Novel Heterocyclic Azo Dyes Derived from Benzothiazole
dc.typeArticle
dspace.entity.typePublication
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The synthesized dyes were characterized by elemental analysis, high‐resolution mass spectrometry, Fourier transform infrared, and NMR spectral techniques. Moreover, we investigated the substituent effect and solvatochromic properties of the dyes on absorption and fluorescence spectra. 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