Browsing by Author "Isinkaralar, Kaan"

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A Study on the Gaseous Benzene Removal Based on Adsorption onto the Cost-Effective and Environmentally Friendly Adsorbent.
(2023-04-13T00:00:00Z) Isinkaralar, Kaan
Removal of benzene is essential for human and environmental health because it has toxic and hazardous properties at various concentrations. Theseneed to be effectively eliminated with carbon-based adsorbents. PASACs, carbon-based adsorbents obtained from using the needles of , were produced by optimized HCl- and HSO-impregnated approaches. Regarding physicochemical structure, the optimized PASAC23 and PASAC35 with surface areas of 657 and 581 m/g and total pore volumes of 0.36 and 0.32 cm/g showed ideal temperatures of 800 °C. In order to investigate and compare internal benzene removal efficiency, PASAC23 and PASAC35 were studied separately. Initial concentrations were found to range from 5 to 500 mg/m, and between 25 and 45 °C. The removal rate of benzene by PASAC23 and PASAC35 was 97 and 94% at low concentrations, respectively. While the highest capture amount for PASAC23 and PASAC35 was found to be at 25 °C with 141 and 116 mg/g, the adsorption capacity decreased to 102 and 90 mg/g at 45 °C. The holding capacity decreased between 22.41 and 27.66% due to increasing temperatures. After five cycles of PASAC23 and PASAC35 regeneration, we found that they could remove 62.37 and 58.46% of benzene, respectively. These results confirmed that PASAC23 is a promising environmentally adsorbent for effectively removing benzene with a competitive yield.
Accumulation analysis and overall measurement to represent airborne toxic metals with passive tree bark biomonitoring technique in urban areas.
(2024-07-03) Isinkaralar, Kaan; Isinkaralar, Oznur; Koc, Ismail; Cobanoglu, Hatice; Canturk, Ugur
Authorities have long proved the utility of bioindicators in monitoring the state of environmental pollution. Some biological indicators can measure environmental pollutant levels, and many tree species have been tested for suitability for monitoring purposes. The differences in morphological characteristics in the trees have demonstrated the effects of human activities on different materials. Measuring bark and wood biomass from contaminated sites was identified and directly compared with those from a clean site or areas characterized by distinct contamination sources. However, preliminary results demonstrate the approach's potential in the realization of strategies for disease control and promoting health to reduce environmental and health inequalities in at-risk urban areas. Picea orientalis L. and Cedrus atlantica Endl., especially their bark, can be regarded as a more robust storage of Cu (37.95 mg/kg) and Mn (188.25 mg/kg) than Pinus pinaster, Cupressus arizonica, and Pseudotsuga menziesii, which and is therefore a better bioindicator for Cu and Mn pollution. Considering the total concentrations as a result of the study, the pollution is thought to be caused by environmental problems and traffic in the region. The deposition of Cu, Mn, Ni, and Zn elements was found P. menziesii (60, 443, 58, and 258 mg/kg) and P. orientalis (76, 1684, 41, and 378 mg/kg) and seems to reflect atmospheric quite clearly compared to P. pinaster, C. arizonica, and C. atlantica. Ni and Zn concentrations have significantly increased since 1983, and P. menziesii and P. orientalis can be potentially valuable bioindicators for emphasizing polluted fields.
Adsorption Behavior of Multi-Component BTEX on the Synthesized Green Adsorbents Derived from Abelmoschus esculentus L. Waste Residue.
(2023-04-24T00:00:00Z) Isinkaralar, Kaan; Meruyert, Keikimanova
Benzene, toluene, ethylbenzene, and xylene (BTEX) removal is one of the most common difficulties in air pollution control. They are emitted from several processes, prejudicial to the environment and humans. BTEX leads to various environmental risks, and there is a significant need for a creating process for the complete removal of BTEX from air streams. This study's objective is the multi-component adsorption of BTEX pollutants from an air stream, by synthesizing activated carbons (ACs) under several operations. A lignocellulosic waste biomass, Abelmoschus esculentus L. (AE), was utilized as the precursor for synthesizing activated carbons (AE-ACs), and their surface chemical characteristics were investigated. Optimization processes were examined, and the change in the surface area of AE-ACs was investigated as change of some variables results like activation agent, impregnation ratio, temperature, and activation time. The maximum surface area of 968 m/g and total pore volume of 0.51 cm/g were attained at 1:2 impregnation ratio, activation time of 110 min, and activation temperature of 800 °C, under N atmosphere. A mixture of BTEX pollutants was employed to consider the effect of humidity (0.5, 1, 1.5, and 2 wt%) and initial concentrations (from 5 to 300 mg/m), using a contact time of 120 min at the temperature of 25 °C. Under the studied conditions, the multi-component and single-component BTEX adsorption capacities by HCl-activated carbon, AE-AC, were specifically achieved to 6.86-51.36 mg/g and 22-93.62 mg/g, respectively. Overall, Abelmoschus esculentus L. was exploited for the synthesis of AE-AC which was successfully utilized for efficient BTEX capture from a polluted air stream.
Comparison of the rate of certain trace metals accumulation in indoor plants for smoking and non-smoking areas.
(2023-05-25T00:00:00Z) Ghoma, Wasem Esmael Omer; Sevik, Hakan; Isinkaralar, Kaan
Tobacco smoke causes to release severe toxic metals into the environment. It is recognized as the most significant issue in indoor air quality. Pollution and toxic substances in smoke quickly spread and penetrate the indoor environment. Environmental tobacco smoke is responsible for lowering indoor air quality. There is much evidence that poor air quality occurs with inadequate ventilation conditions in indoor environments. The plants have been observed to absorb the smoke in the environment into their own body like a sponge. The plant species in this study can be used easily in almost every office, home, or other indoor areas. Using indoor plants is very beneficial in biomonitoring and absorbing these trace metals. Some indoor plants have shown successful performance as biomonitors for health-damaging pollutants. The study aims to determine the concentration of three trace metals (Cu, Co, and Ni) using five indoor ornamentals frequently used in smoking areas, namely D. amoena, D. marginata, F. elastica, S. wallisii, and Y. massengena. The Ni uptake and its accumulation in S. wallisii, and Y. massengena increased in correlation with smoke areas. However, the rate of accumulation of Co and Cu was found to be independent due to consideration of the environmental emissions. Consequently, our results suggest that F. elastica is more resistant to smoking, whereas S. wallisii would be a better choice as a biomonitoring plant of tobacco smoke.
Detection of landscape species as a low-cost biomonitoring study: Cr, Mn, and Zn pollution in an urban air quality.
(2022-08-18T00:00:00Z) Yayla, Emine Emel; Sevik, Hakan; Isinkaralar, Kaan
Urban air pollution in cities, among the world's most critical problems, has escalated to such an extent that it threatens human health in many urban centers and causes the death of millions every year. Trace metals are significant among the components of air pollution. Trace metals can endure long without undergoing biodegradation and bioaccumulation in living organisms. Moreover, their concentration in the air increases gradually. Therefore, monitoring metal concentration is extremely important for reliable indicators of environmental pollution. Biomonitoring is an effective method for describing metal concentrations in urban areas. Chromium, manganese, and zinc, selected within the present study, have various adverse effects on plants in high concentrations. Their identification is highly critical for monitoring the pollution level in their regions. This study aimed to determine the Cr, Mn, and Zn concentration changes according to organ, and age in Elaeagnus angustifolia L., Platanus orientalis L., Koelreuteria paniculata Laxm, Ailanthus altissima (Mill.) Swingle, and Cedrus atlantica (Endl.) Manetti ex Carr is 30 years old. The accumulation of metals in the outer bark can be found as follows Zn > Mn > Cr in all species, although Ailanthus altissima (Mill.) Swingle and Platanus orientalis L. can be suitable for biomonitoring tools because concentrations change significantly depending on the airborne metal.
High-efficiency removal of benzene vapor using activated carbon from Althaea officinalis L. biomass as a lignocellulosic precursor.
(2022-09-01T00:00:00Z) Isinkaralar, Kaan
Benzene is a primary air pollutant commonly found widespread in the indoor environment. It has always been a research focus on the environment due to the causes of significant human health concerns. It has been widely utilized in the synthesis of solvent production, which can rarely be found in high concentrations in outdoor air or high amounts in indoor air, depending on its sources. It is aimed to remove different initial benzene concentrations (from 5 to 1500 ppm) with the production of activated carbon as an excellent adsorbent with a high surface area to be used in these situations. Lignocellulosic wastes have great potential for activated carbon for their advantages (abundant, recycled, and low-cost materials, etc.). This study aimed to evaluate biowaste material for activated carbon production from Althaea officinalis L. biomass by chemical activation (HSO, LiOH, and ZnCl) at temperatures between 500 and 900 °C. Newly developed powdered activated carbons (Ao-ACs) are also tabulated as Ao-AC1-45 for easy reference. Benzene vapor was collected into Tenax TA® tubes by automatic thermal desorption in conjunction with a capillary gas chromatography-mass spectrometry (TD-GC/MS). The significant surface area and production yield of Ao-ACs were obtained at 1424 m/g (Ao-AC43) and up to 40.32%, respectively. The maximum gas-phase benzene adsorption capacity was 140 mg/g at 270 min. This research has focused on adsorption gas-phase benzene removal onto Ao-ACs as a low-cost adsorbent from the Althaea officinalis L. biomass. Conspicuously, more study is needed to perform the enhanced adsorption of airborne pollutants capacity with inexpensive activated carbon from waste biomass materials.
High-efficiency removal of benzene vapor using activated carbon from Althaea officinalis L. biomass as a lignocellulosic precursor.
(2022-09-01T00:00:00Z) Isinkaralar, Kaan; Isinkaralar, K
Benzene is a primary air pollutant commonly found widespread in the indoor environment. It has always been a research focus on the environment due to the causes of significant human health concerns. It has been widely utilized in the synthesis of solvent production, which can rarely be found in high concentrations in outdoor air or high amounts in indoor air, depending on its sources. It is aimed to remove different initial benzene concentrations (from 5 to 1500 ppm) with the production of activated carbon as an excellent adsorbent with a high surface area to be used in these situations. Lignocellulosic wastes have great potential for activated carbon for their advantages (abundant, recycled, and low-cost materials, etc.). This study aimed to evaluate biowaste material for activated carbon production from Althaea officinalis L. biomass by chemical activation (HSO, LiOH, and ZnCl) at temperatures between 500 and 900 °C. Newly developed powdered activated carbons (Ao-ACs) are also tabulated as Ao-AC1-45 for easy reference. Benzene vapor was collected into Tenax TA® tubes by automatic thermal desorption in conjunction with a capillary gas chromatography-mass spectrometry (TD-GC/MS). The significant surface area and production yield of Ao-ACs were obtained at 1424 m/g (Ao-AC43) and up to 40.32%, respectively. The maximum gas-phase benzene adsorption capacity was 140 mg/g at 270 min. This research has focused on adsorption gas-phase benzene removal onto Ao-ACs as a low-cost adsorbent from the Althaea officinalis L. biomass. Conspicuously, more study is needed to perform the enhanced adsorption of airborne pollutants capacity with inexpensive activated carbon from waste biomass materials.
Monitoring the spatial distribution pattern according to urban land use and health risk assessment on potential toxic metal contamination via street dust in Ankara, Türkiye.
(2023-08-24) Isinkaralar, Oznur; Isinkaralar, Kaan; Bayraktar, Emine Pirinç
The urbanization processes with growing vehicle numbers cause heavy metal pollution in street dust, and high populations in metropolitan cities are exposed to pollutants. This paper aims to monitor the spatial distribution of heavy metals and evaluate the concentrations via health risk assessment of HMs (Cu, Ni, Cd, Co, Pb, and Zn) that expose the inhabitants to health hazards. According to the results of the current study, sixty street dust samples were applied to the acid digestion technique and quantification by inductively coupled plasma-mass spectrometry (ICP-MS). The spatial distribution of the selected heavy metals in the street dust was investigated using the spatial analysis tool in ArcGIS 10.0 according to population density and land use. In the present study, we used hazard index and cancer risk methods to estimate the public health risk of the pollutants exposed to street dust in Ankara. The concentrations range of the elements in street dust over the study area ranged from 3.34-4.50, 31.69-42.87, 16.09-21.54, 42.85-57.55, 0.00-3.51, and 23.03-30.79, respectively. The overall decreasing order of mean concentration of metals was observed as follows: Pb > Cu > Ni > Co > Cd > Zn. Vehicle traffic and industrial activities seem to be the most critical anthropogenic sources responsible for dust pollution in the study area. The risk assessment of Pb and Ni exposure was the highest, and the hazard index values were 2.42E + 00 and 2.28E + 00 mg/kg/day for children. However, the effect on adults was 2.62E-01 and 2.37E-02 mg/kg/day, followed by inhalation and dermal contact with street dust was almost negligible. The decreasing concentration is modeled spatially along the western development corridor of the city. The risk to public health is high in areas with high densities close to the city center and the main artery.
Spatial Distribution of Heavy Metal Contamination in Road Dust Samples from an Urban Environment in Samsun, Türkiye.
(2023-04-09T00:00:00Z) Istanbullu, Seyma Nur; Sevik, Hakan; Isinkaralar, Kaan; Isinkaralar, Oznur
Road dust is an environmental pollution indicator created by human activities for urban land use. This study aimed to determine the spatial distribution pattern and degree of trace metals in road dust samples collected from 5 different areas in Samsun city center. The trace metals of Mn, Co, Cd, Cr, Cu, Ni, Pb, and Zn are the most examined contaminants in road dust because their hot-spot areas were mainly associated with high traffic density. Factors governing potential contamination index range values of Co, Cr, and Ni were 0.34-0.62, 0.23-0.78, and 0.24-0.48 as the lowest contamination. However, potential contamination index values of Cu, Pb, and Zn in the main road site were 1.80, 2.32, and 2.84 suggesting that relatively high values were uncontaminated to moderately. Pollution assessment methods were applied to toxic metals and revealed that Samsun city had been affected as uncontaminated to moderately contaminated by anthropogenic emission of heavy metals.
Spatial distribution, pollution level and human health risk assessment of heavy metals in urban street dust at neighbourhood scale.
(2024-07-02) Isinkaralar, Oznur; Isinkaralar, Kaan; Nguyen, Tuyet Nam Thi
Urban street dust (UStD) is a vital issue for human health and is crucial for urban sustainability. This study aims to enhance the creation of safe, affordable, and resilient cities by examining environmental contamination and health risks in urban residential areas. Specifically, it investigates the concentrations and spatial distribution of chromium (Cr), cadmium (Cd), nickel (Ni), copper (Cu), lead (Pb), and zinc (Zn) in UStD in Yenimahalle, Ankara. The mean concentrations of Zn, Cr, Pb, Cd, Ni, and Cu in UStD were 97.98, 66.88, 55.22, 52.45, 38.37, and 3.81 mg/kg, respectively. The geoaccumulation pollution index (Igeo) values for these elements were: Cd (5.12), Ni (1.61), Cr (1.21), Pb (1.13), Cu (0.78), and Zn (0.24). These indices indicate that the area is moderately polluted with Cr, Pb, and Ni, uncontaminated to moderately contaminated with Cu and Zn, and extremely polluted with Cd. The hazard index (HI) values for Cr, Cd, Ni, Cu, Pb, and Zn were below the non-carcinogenic risk threshold for adults, indicating no significant risk. However, for children, the HI values for Pb, Ni, Cd, and Zn were 3.37, 1.80, 1.25, and 1.25, respectively, suggesting a higher risk. Carcinogenic risk (RI) of Cd, Ni, and Pb was significant for both children and adults, indicating that exposure through ingestion, inhalation, and dermal contact is hazardous. The findings highlight the need for strategic mitigation measures for both natural and anthropogenic activities, providing essential insights for residents, policymakers, stakeholders, and urban planners.
The potential of using Cedrus atlantica as a biomonitor in the concentrations of Cr and Mn.
(2021-10-01T00:00:00Z) Savas, Duygu Seda; Sevik, Hakan; Isinkaralar, Kaan; Turkyilmaz, Aydin; Cetin, Mehmet
Air pollution is becoming increasingly dangerous which is quite a significant issue of today's world, especially air pollution from heavy metal, whose emission increases with industrial and traffic activities. This is of great importance in terms of environmental pollution and human health. Heavy metals do not deteriorate and disappear easily on earth. They are liable to bioaccumulate within cells in organisms. Most of them demonstrate harmful effects in addition as a result of advanced accumulation, and thus they emerge as toxic and carcinogenic. Therefore, it is of great importance to observe the changes in heavy metal concentrations in the air. One of the most effective techniques for monitoring the change of heavy metal concentrations in the atmosphere is the use of annual rings of trees as biomonitors. In this study, in the annual rings of the Cedrus atlantica Manetti tree cut at the Kastamonu province at the end of 2019, the variation of the concentrations of some of the heavy metals most associated with traffic density was tried to be determined. Within the scope of the study, Cr and Mn concentration in the outer bark and the inner bark was compared with the direction and wood for the variation of heavy metal concentrations. Also, variance analysis and Duncan test were applied and evaluated. As a result of the study, while the highest values in many heavy metals are generally obtained in the outer bark, the transfer of metals in the wood is limited, and some heavy metal concentrations change significantly depending on the direction, especially in the wood. This change is related to the traffic density, so Cedrus atlantica Manetti annual rings are very suitable as biomonitors for air pollution control.
Toxic metal accumulation, health risk, and distribution in road dust from the urban traffic-intensive environment.
(2024-10-11) Isinkaralar, Oznur; Isinkaralar, Kaan; Nguyen, Tuyet Nam Thi
Owing to increasing levels of potentially toxic metals in road dust, air pollutants suspended in the air, pose significant health risks due to rapid, unplanned urbanization and industrialization. This study investigated the pollution status and health risks of trace metals (i.e., Cr, Cd, Ni, Cu, and Pb) in road dust collected from 16 locations across six land-use categories in Eskişehir, Türkiye, including residential, roadside, traffic, tram stations, and car industrial areas. The analysis of trace metals revealed distinct types of urban pollution based on these functional areas. In areas with heavy traffic, high concentrations of the elements, especially Zn, Cr, and Ni, would indicate significant toxic metal pollution. The overall contamination was evaluated using three indices: enrichment factor (EF 0.45-65.75), geo-accumulation index (I - 2.50-4.18), and pollution index (PI 0.27-27.22). Human health risks of potentially toxic trace metals in urban road dust were evaluated for children and adult groups based on hazardous index (HI) and total cancer risk (TCR). The health risk assessments revealed that children (mean HI 8.62E - 01; TCR 6.99E + 04) are more vulnerable to toxic metal exposure than adults (mean HI 1.01E - 01; TCR 3.01E + 04), with ingestion being the primary exposure route over dermal contact and inhalation. In conclusion, we have captured the interaction between road dust and health risks, especially for children.
Use of tree rings as a bioindicator to observe atmospheric heavy metal deposition.
(2019-02-01T00:00:00Z) Turkyilmaz, Aydin; Sevik, Hakan; Isinkaralar, Kaan; Cetin, Mehmet
Trees can be used as good indicators to evaluate the increase in atmospheric heavy metal concentrations. In the last two decades, air pollution in the city of Ankara has rapidly increased with the ever-increasing traffic density. In the present study, the depositions of aluminum (Al), zinc (Zn), copper (Cu), cobalt (Co), iron (Fe), manganese (Mn), chrome (Cr), cadmium (Cd), sodium (Na), calcium (Ca), barium (Ba), phosphor (P), magnesium (Mg), arsenic (As), and boron (B) in the rings of oak trees were analyzed using a GBC Integra XL-SDS-270 ICP-OES device. The study found that heavy metal concentrations in tree rings varied over the past 20 years; furthermore, there was a significant relationship between the heavy metal concentrations in tree rings and the atmospheric heavy metal concentrations. There was an increase in the concentrations of nutritional elements (Na, P, and Mg) in 2010 when there was excessive precipitation. As a result, the concentrations of all elements in the woods of different ages were significantly different at a confidence interval of 95% for As, 99% for Cd, and 99.9% for other elements.
Using Acer platanoides annual rings to monitor the amount of heavy metals accumulated in air.
(2018-09-08T00:00:00Z) Turkyilmaz, Aydin; Sevik, Hakan; Isinkaralar, Kaan; Cetin, Mehmet
Annual rings are good indicators for determining the increase in the amount of heavy metals in the atmosphere from past to the present. Air pollution has rapidly increased in Ankara over the past 20 years. In particular, there is a serious increase in the concentration of heavy metals that adversely affect human health. In this study, the accumulation of Al, Zn, Cu, Co, Fe, Mn, Cr, Cd, Na, Ca, Ba, P, Mg, As, and B on Acer platanoides rings has been determined using the GBC Integra XL-SDS-270 ICP-OES instrument. Based on our experimental findings, we determined that the concentration of heavy metals accumulated on the rings over the past 20 years varied and that there was a significant correlation between heavy metal concentration in air and heavy metal accumulation on trees. The main reasons for this increase were an increase in the amount of exhaust emission gases and most importantly the transport of heavy metals by the prevailing winds from heavy industrial plants established after 1990 in Ankara. As a result, when the values were examined, we found that except for Na, all the elements, which showed differences at statistically significant levels, were in considerably high quantities in the bark. On average, the values obtained for bark were 6 times higher than those obtained for wood. In terms of elements that showed statistically significant level of differences, this difference was the lowest in P (1.61 times higher), Mg (2.52 times higher), and B (3.94 times higher) and the highest in Mn (23.87 times higher), Al (22.0 times higher), and Fe (14.27 times higher). In the case of Na, we found that the value obtained for wood was 1.64 times higher than that obtained for bark.