Browsing by Author "Dogruer M."
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Scopus A comprehensive study on mechanical properties of Bi1.8Pb 0.4Sr2MnxCa2.2Cu3.0O y superconductors(2013-08-01) Dogruer M.; Karaboga F.; Yildirim G.; Terzioglu C.; Ozturk O.This study manifests the crucial change in the mechanical performances of Bi1.8Pb0.4Sr2MnxCa 2.2Cu3.0Oy superconductor samples (x = 0, 0.03, 0.06, 0.15, 0.3 and 0.6) prepared by conventional solid-state reaction method by use of Vickers microhardness (Hv) measurements carried out at different applied loads, (0.245 N ≤ F ≤ 2.940 N). Load dependent microhardness, load independent microhardness, Young's (elastic) modulus and yield strength values being account for the potential technological and industrial applications are evaluated from the hardness curves and compared with each other. It is found that the Hv, elastic modulus and yield strength obtained decrease (increase) with the enhancement of the applied load for the undoped (doped) samples. Surprisingly, the results of the Hv values illustrate that the samples doped with x = 0.03, 0.06, 0.15, 0.3 and 0.6 exhibit reverse indentation size effect (RISE) feature whereas the pure sample obeys indentation size effect (ISE) behavior. Furthermore, the experimental results are examined with the aid of the available methods such as Meyer's law, proportional sample resistance model (PSR), elastic/plastic deformation (EPD), Hays-Kendall (HK) approach and indentation-induced cracking (IIC) model. The results inferred show that the hardness values calculated by PSR and EPD models are far from the values of the plateau region, meaning that these models are not adequate approaches to determine the real microhardness value of the Mn doped Bi-2223 materials. On the other hand, the HK approach is completely successful for the explanation of the ISE nature for the pure sample while the IIC model is obtained to be the best model to describe the hardness values of the doped materials exhibiting the RISE behavior. Additionally, the bulk porosity analysis for the samples reveals that the porosity increases monotonously with the increment in the Mn inclusions inserted in the Bi-2223 system, presenting the degradation of the grain connectivity. © 2013 Springer Science+Business Media New York.Scopus A study on magnetoresistivity, activation energy, irreversibility and upper critical field of slightly Mn added Bi-2223 superconductor ceramics(2012-05-01) Dogruer M.; Zalaoglu Y.; Varilci A.; Terzioglu C.; Yildirim G.; Ozturk O.This study discusses the effect of Mn addition on the superconducting and physical properties in Bi 1.8Pb 0.4Sr 2Mn xCa 2.2Cu 3.0O y bulk superconductors with x = 0, 0.03,0.06,0.15, 0.3, and 0.6 by means of themagne-toresistivity measurements. The magnetoresistivity of the samples prepared using the standard solid-state reaction method was measured for different values of the applied magnetic field strengths. The superconducting and physical properties of the samples such as the zero resistivity transition temperatures (T c), irreversibility fields (μ 0Hi rr), and upper critical fields (μ 0H c2) were deduced from the magnetoresistivity curves. Moreover, thermally activated flux creep model was studied for activation energy (U0) values of the samples. According to the results of the measurements, not only were the T c and U0 values of the samples found to decrease significantly but the μ 0Hi rr and μ 0H c2 values were also observed to reduce with the increase in the Mn addition, indicating that the doping degrades the physical and superconducting properties of the samples. © 2012 Springer Science+Business Media, LLC.Scopus Analysis of indentation size effect on mechanical properties of Cu-diffused bulk MgB2 superconductor using experimental and different theoretical models(2013-01-01) Dogruer M.; Yildirim G.; Ozturk O.; Terzioglu C.This study indicates the change of the electrical, microstructural, physical, mechanical and superconducting properties of Cu-diffused bulk MgB 2 superconductors by means of scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), microhardness and dc resistivity measurements. The samples are prepared at different annealing temperatures in the range from 650 to 850 â̂̃C. Electrical and superconducting properties of samples are estimated from the dc electrical resistivity measurements. Moreover, microhardness measurements are performed to investigate the mechanical properties. Further, phase composition, grain sizes and lattice parameters are determined from the XRD measurements. At the same time, the surface morphology and grain connectivity of the samples are examined by SEM investigations. The measurements conducted demonstrate that both the Cu diffusion into the MgB2 system and the increment in the diffusion-annealing temperature increase the critical transition temperatures. Similarly, microstructure and grain size improve while the voids and porosity decrease with the increase of the diffusion-annealing temperature. In addition, the experimental results of the microhardness measurements are investigated using the Meyer's law, PSR (proportional specimen resistance), modified PRS (MPSR), elastic-plastic deformation model (EPD) and Hays-Kendall (HK) approach. The obtained microhardness values of the samples decrease with the increase of the diffusion-annealing temperature up to 850 â̂̃C. The Hays-Kendall approach is found to be the most successful model describing the mechanical properties of the samples studied in this work. © 2012 Springer Science+Business Media, LLC.Scopus Breaking point of the harmony between Gd diffused Bi-2223 slabs with diffusion annealing temperature(2013-01-01) Aydın H.; Babanli A.; Altintas S.; Asikuzun E.; Soylu N.; Ozturk O.; Dogruer M.; Terzioglu C.; Yildirim G.This comprehensive study reports the role of annealing temperature on the microstructural, superconducting and mechanical characteristics of the Gd diffused Bi-2223 superconducting ceramics produced by the conventional solid-state reaction route at 840 C for the annealing duration of 48 h. For the material characterization, the standard experimental methods such as dc resistivity (ρ-T), transport critical current density, X-ray powder diffraction, scanning electron microscopy and Vickers microhardness measurements are performed systematically. All the results obtained show that all the measured characteristic properties, being in charge of the applications in the industry, engineering and technology, improve until a certain diffusion annealing temperature of 800 C beyond which they tend to degrade considerably. The increase in the properties is mostly related to the transition from the inherent overdoped state of the pure Bi-2223 material to optimum doped state with the diffusion annealing temperature, confirming the penetration of the sufficient Gd nanoparticles into the crystal structure. On the other hand, the suppression in the superconducting properties stems from the appearance of the porosity, defects, disorder and localization problem in the polycrystalline Bi-2223 superconducting matrix. This is attributed to the decrement of the average crystallite size and mobile hole concentration in the Cu-O 2 layers and especially the retrogression of the crystallinity in the system. As for the mechanical characteristics, Vickers microhardness measurements exerted in the applied indentation test load range of 0.245-2.940 N indicate that the Gd diffused bulk superconducting samples exhibit the typical indentation size effect behavior. With the enhancement in the annealing temperature up to 800 C, the significant increase in the elastic modulus, yield strength and fracture toughness is one of the most striking points in the paper. The long and short of it is that the excess diffusion annealing temperature damages the fundamental characteristics of the Bi-2223 system. © 2013 Springer Science+Business Media New York.Scopus Comparative study on mechanical properties of undoped and Ce-doped Bi-2212 superconductors(2013-07-01) Zalaoglu Y.; Bekiroglu E.; Dogruer M.; Yildirim G.; Ozturk O.; Terzioglu C.This study discusses the mechanical performances of Bi1.8Sr 2.0CexCa1.1Cu2.1Oy ceramics with x = 0, 0.001, 0.003, 0.005, 0.01, 0.03, 0.05 and 0.1 by way of Vickers microhardness (Hv) measurements performed at different applied loads in the range of 0.245-2.940 N. For the potential industrial applications, the important mechanical characteristics such as Vickers microhardness, elastic modulus, yield strength, fracture toughness and brittleness index values of the samples studied are extracted from the microhardness measurements. All the results obtained indicate that the Vickers hardness, Young's (elastic) modulus, yield strength, fracture toughness and brittleness index values suppress with the increment of the Ce concentration in the system as a consequence of the degradation in the connectivity between superconducting grains. The decrement in the Hv values with the applied load is attributed Indentation Size Effect behaviour of the samples studied. Moreover, the experimental results of Vickers microhardness measurements are estimated using the 5 different models such as Kick's law, proportional sample resistance model, modified proportional sample resistance model, elastic/plastic deformation model and Hays-Kendall approach. According to the results obtained from the simulations, Kick's law is not useful model to obtain information about the origin of the indentation size effect feature of the Ce-doped bulk Bi-2212 superconductors. On the other hand, the Hays-Kendall approach is determined as the most suitable model for the description of the mechanical properties of the superconducting samples. In addition, the bulk porosity analysis for the samples reveals that the porosity increases monotonously with the Ce inclusion in the Bi-2212, leading to the degradation of the grain connectivity. © 2013 Springer Science+Business Media New York.Scopus Effect of Ce addition on the magnetoresistivity, irreversibility field, upper critical field and activation energies of Bi-2212 superconducting ceramics(2012-05-01) Yildirim G.; Dogruer M.; Ozturk O.; Varilci A.; Terzioglu C.; Zalaoglu Y.This study aims to analyze the effect of Ce addition on the microstructural, superconducting and physical properties of Bi 1.8Sr 2.0CexCa 1.1Cu 2.1O y ceramics with x = 0, 0.001, 0.003, 0.005, 0.01, 0.03, 0.05 and 0.1 via X-Ray analysis (XRD), scanning electron microscopy (SEM), electron dispersive X-Ray (EDX) and magnetoresistivity measurements. The ceramics produced in this work are prepared using the standard solid-state reaction method. The zero resistivity transition temperatures (T c), activation energies (U0), irreversibility fields (μ 0Hi rr) and upper critical fields (μ 0H c2) are determined from the resistivity versus temperature (R-T) curves under dc magnetic fields up to 7 T The results show that T c and U0 values of the samples are found to decrease dramatically with the increase in the Ce-content and applied magnetic field. Moreover, XRD results indicate that all the samples contain the Bi-2212 phase only and exhibit the polycrystalline superconducting phase with less intensity of diffraction lines with the increase of the Ce addition. As for the results of SEM images, the texturing, crystallinity, grain size distribution, layered grain growth and grain connectivity are observed to degrade with the increase of the Ce doping. Besides, the irreversibility fields and upper critical fields are found to degrade as Ce doping increases. Penetration depths (λ) and coherence lengths (ξ) are also discussed. © 2012 Springer Science+Business Media, LLC.Scopus Evaluation of microstructural and mechanical properties of ag-diffused bulk MgB2 superconductors(2014-01-01) Yilmazlar M.; Terzioglu C.; Dogruer M.; Karaboga F.; Soylu N.; Zalaoglu Y.; Yildirim G.; Ozturk O.Electrical, microstructural, and mechanical properties of undiffused and Ag-diffused bulk MgB2 superconductors are systematically studied using dc resistivity, scanning electron microscopy (SEM), and Vickers microhardness (H V ) measurements. The resistivity (at room temperature), critical (onset and offset) temperature, variation of transition temperature, hole-carrier concentration, surface morphology, Vickers microhardness, elastic modulus, and yield strength values of the samples are obtained and compared with each other. One can see that all superconducting parameters given above depend on the Ag diffusion on MgB2 system. The obtained results illustrate that the room temperature resistivity reduces with the increment of diffusion annealing temperature because of the hole filling when the onset (Tconset) and offset (Tcoffset) critical temperatures determined from the resistivity curves are obtained to enhance from 38.4 to 39.7 K and from 36.9 to 38.8 K, respectively. Further, SEM studies carried out for the microstructural characterization demonstrate that the surface morphology and grain connectivity also improve with the increase of the diffusion annealing temperature. In fact, the best surface morphology is observed for the Ag-diffused bulk MgB2 superconductor exposed to 850 C annealing temperature. Besides, it is obtained that the load-dependent microhardness values reduce nonlinearly as the applied load increases until 2 N, beyond which the curves shift to the saturation region, presenting that all the samples exhibit the indentation size effect (ISE) behavior. Further, the elastic modulus and yield strength values observed decrease with the enhancement of the applied load. © 2013 Springer Science+Business Media New York.Scopus Influence of diffusion-annealing temperature on physical and mechanical properties of Cu-diffused bulk MgB2 superconductor(2013-02-01) Dogruer M.; Zalaoglu Y.; Gorur O.; Ozturk O.; Yildirim G.; Varilci A.; Yucel E.; Terzioglu C.This study reports not only the effect of Cu diffusion on physical and mechanical properties of bulk MgB2 superconductors with the aid of Vickers microhardness (Hv) measurements but also the diffusion coefficient and the activation energy of copper (Cu) in the MgB2 system using the resistivity measurements for the first time. Cu diffusion is examined over the different annealing temperature such as 650, 700, 750, 800 and 850 C via the successive removal of thin layers and resistivity measurement of the sample. Further, Vickers microhardness, elastic modulus, yield strength, fracture toughness and brittleness index values of the samples studied are evaluated from microhardness measurements. It is found that all the results obtained depend strongly on the diffusion annealing temperature and applied load. The microhardness values increase with ascending the annealing temperature up to 850 C owing to the increment in the strength of the bonds between grains but decreasing with the enhancement in the applied load due to Indentation Size Effect behaviour of the bulk samples. Moreover, the diffusion coefficient is observed to enhance from 2.84 × 10-8 to 3.22 × 10 -7 cm2 s-1 with the increase of the diffusion-annealing temperature, confirming that the Cu diffusion is more dominant at higher temperatures compared to lower ones. Besides, temperature dependence of the Cu diffusion coefficient is described by the Arrhenius relation D = 2.66 × 10-3 exp(-1.09 ± 0.05 eV/k BT) and the related activation energy of the Cu ions in the MgB 2 system is obtained to be about 1.09 eV. Based on the relatively low value of activation energy, the migration of the Cu ions primarily proceeds through defects such as pore surfaces and grain boundaries in the polycrystalline structure, resulting in the improvement of the physical and mechanical properties of the bulk MgB2 samples. © 2012 Springer Science+Business Media, LLC.Scopus Influence of Sr/Nd partial replacement on fundamental properties of Bi-2223 superconducting system(2021-03-01) Dogruer M.; Aksoy C.; Yildirim G.; Ozturk O.; Terzioglu C.This comprehensive work aims to examine the change in flux pinning mechanism, physical, mechanical, and structural characteristics of pure and Sr-site Nd-substituted Bi1.8Pb0.35Sr1.9−yNdyCa2.2Cu3Ox (Bi-2223) systems. The magnetoresistivity performances for all the samples are carried out by magnetotransport experiments in the existence of external magnetic field strength intervals 0–7 T. It is found that the increment of Nd/Sr substitution amount in bulk Bi-2223 system retrogrades the pinning capability of thermal flux motions for interlayer Josephson junction between the isolated grains. Similarly, the coupling probabilities of copper pairs and potential energy barriers are significantly diminished by increasing Nd impurity. This is in association with the enhancement of permanent structural problems in the crystal structure. Therefore, the excessive Nd inclusions improve the reattached linear/split pancake-like nature. In this regard, the best magnetic performance quantities are obtained for the pure sample. Besides, the SEM images show that the grain connectivity and surface morphology damage significantly with the Nd impurity. Additionally, the experimental microhardness findings conducted at various external loads (0.245–2.940 N) display that the Nd purity in the superconducting system degrades dramatically the key design mechanical features. Besides, we analyze the mechanical characteristic properties founded on the theoretical approaches with the proportional sample resistance, elastic/plastic deformation, and Hays–Kendall methods. The results obtained show that the Nd purity causes the indentation size effect behavior to decrease dramatically for all the samples. Furthermore, the findings of Hays–Kendall method are noticed to much more agree with the real hardness parameters. Thus, the Hays–Kendall model is the best methods to find the load-independent Vickers hardness values for the Sr-site Nd-substituted Bi1.8Pb0.35Sr1.9−yNdyCa2.2Cu3Ox (Bi-2223) systems. Moreover, in the dynamic microhardness measurements, the contact depth (hc), elastic modulus (Er), and load (Pmax) of all the samples are experimentally recorded for the first time. The results reveal that the mechanical properties depend strongly on the load and Nd impurity level.Scopus Investigation of microstructural, Vickers microhardness and superconducting properties of YBa2Cu3-xGdxO 7-δ (0 ≤ x ≤ 0.150) superconducting ceramics via experimental and theoretical approaches(2013-04-01) Dogruer M.; Yildirim G.; Ozturk O.; Varilci A.; Soylu N.; Gorur O.; Terzioglu C.This study manifests the change of pinning mechanism, electrical, structural, physical, mechanical and superconducting properties of YBa 2Cu3-xGdxO7-δ superconductors samples prepared by the conventional solid-state reaction method (x = 0, 0.025, 0.050, 0.100 and 0.150) by use of dc resistivity, X-ray analysis (XRD), scanning electron microscopy (SEM) and Vickers microhardness measurements. Zero resistivity transition temperatures (T coffset ) of the samples are deduced from the dc resistivity measurements. Additionally, the lattice parameters are determined from XRD measurements when the microstructure, surface morphology and microhardness of the samples studied are examined by SEM and mechanical measurements, respectively. The results obtained demonstrate that T coffset values of the samples decrease slowly with the increase in the Gd content. The maximum T coffset (92.0 K) is obtained for the pure sample prepared at 940 C for 20 h in air atmosphere while the minimum value of 83.3 K is found for the sample doped with 0.150 Gd content. Moreover, it is obtained that J c values reduce from 132 to 34 A/cm2 with the enhancement of the Gd level in the crystalline structure. Further, the peak intensities belonging to Y123 (major) phase are obtained to decrease whereas the peak intensities of the minor phases such as BaCuO2 and Y211 are found to enhance systematically with the increment in the Gd content in the system, illustrating that partial substitution of Cu2+ ions by Gd3+ ions are carried out successfully. Moreover, SEM images display that the undoped sample obtains the best crystallinity and connectivity between superconducting grains and largest grain size whereas the worst surface morphology is observed for the maximum doped sample (x = 0.150). At the same time, Vickers microhardness, elastic modulus, load independent hardness, yield strength, fracture toughness and brittleness index values, playing important roles on the mechanical properties, are computed for all the samples. The experimental results of the microhardness measurements are examined using the Meyer's law, PSR (proportional specimen resistance), modified PRS, Elastic-Plastic deformation model (EPD) and Hays-Kendall (HK) approach. The microhardness values obtained increase with the enhancement of the Gd content in the samples. Besides, it is noted that the Hays-Kendall approach is the most successful model explaining the mechanical properties of the samples studied in this work. © 2012 Springer Science+Business Media New York.Scopus Role of diffusion-annealing time on the superconducting, microstructural and mechanical properties of Cu-diffused bulk MgB2 superconductor(2013-01-01) Dogruer M.; Gorur O.; Zalaoglu Y.; Ozturk O.; Yildirim G.; Varilci A.; Terzioglu C.In this study, the effect of various annealing time (0.5, 1, 1.5 and 2 h) on microstructural, mechanical and superconducting properties of the Cu-diffused bulk MgB2 superconducting samples is investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Vickers microhardness (H v ) and dc resistivity measurements for the first time. The critical transition temperature, grain size, phase purity, lattice parameter, surface morphology, crystallinity and room temperature resistivity values of the bulk samples prepared are compared with each other. Electrical-resistivity measurements show that the sample (annealed at 850 C for 1 h), exhibiting the highest room temperature resistivity, obtains the maximum zero resistivity transition temperature (T c ). From the XRD results, all the samples contain MgB2 as the main phase with a very small amount of Mg 2Cu phase. Moreover, SEM investigations conducted for the microstructural characterization illustrate that not only does the grain size of the samples studied enhance gradually, but the surface morphology and grain connectivity also improve with the increase in the diffusion-annealing time up to 1 h beyond which all the properties obtained start to degrade. Indeed, the worst surface morphology is observed for the Cu-diffused bulk MgB2 superconductor exposed to 2 h annealing duration. At the same time, Vickers microhardness, elastic modulus, load independent hardness, yield strength, fracture toughness and brittleness index values are calculated separately for the pure and Cu-diffused samples. It is found that the microhardness values depend strongly on the diffusion-annealing time. Furthermore, the diffusion coefficient of the Cu ion in the bulk MgB2 superconductor is obtained to change from 1.63 × 10-7 to 2.58 × 10-7 cm2 s-1. The maximum diffusion coefficient is observed for the sample prepared at 850 C for 1 h whereas the minimum one is noted for the sample annealed at 850 C for 2 h, confirming that the annealing-time of 1 h is the best ambient to improve the mechanical, microstructural and superconducting properties of the samples produced. © 2012 Springer Science+Business Media, LLC.Scopus Theoretical investigations of α,α,α-trifluoro-3, -p and o-nitrotoluene by means of density functional theory(2012-01-01) Yildirim G.; Senol S.; Dogruer M.; Ozturk O.; Senol A.; Tasci A.; Terzioglu C.This study reports the optimized molecular structures, vibrational frequencies including Infrared intensities and Raman activities, corresponding vibrational assignments, 1H and 13C NMR chemical shifts, the magnitudes of the JCH and JCC coupling constants, Ultraviolet-visible (UV-vis) spectra, thermodynamic properties and atomic charges of the title compounds, α,α,α-trifluoro-3, -p and o-nitrotoluene, in the ground state by means of the density functional theory (DFT) with the standard B3LYP/6-311++G(d,p) method and basis set combination for the first time. Theoretical vibrational spectra were interpreted by normal coordinate analysis based on scaled density functional force field. The results show that the vibrational frequencies and chemical shifts calculated were obtained to be in good agreement with the experimental data. Based on the comparison between experimental results and theoretical data, the calculation level chosen is powerful approach for understanding the identification of all the molecules studied. In addition, not only were frontier molecular orbitals (HOMO and LUMO), molecular electrostatic potential (MEP) and electrostatic potential (ESP) simulated but also the dipole moment, softness, electronegativity, chemical hardness, electrophilicity index, transition state and energy band gap values were predicted. According to the investigations, all compounds were found to be useful to bond metallically and interact intermolecularly; however, the thermodynamic properties confirm that the α,α,α-trifluoro-p- nitrotoluene was more reactive and more polar than the others. © 2011 Elsevier B.V. All rights reserved.Scopus Variation of mechanical properties of Cr doped Bi-2212 superconductors(2013-09-01) Dogruer M.; Yildirim G.; Ozturk O.; Belenli I.; Terzioglu C.This study shows the influence of Cr inclusions on the mechanical properties of Bi1.8Sr2.0Crx Ca 1.1Cu2.1Oy (Bi-2212) superconducting samples (x=0, 0.1, 0.3, 0.5, 0.7, and 1) prepared by conventional solid-state reaction route with the aid of the microhardness (Hv) measurements. Moreover, some characteristics such as Vickers microhardness, Young's (elastic) modulus (E) and yield strength (Y), being responsible for the potential technological and industrial applications, are theoretically evaluated from the microhardness curves belonging to the samples and compared with each other. It is found that the load dependent microhardness values decrease nonlinearly as the applied load enhances until 2 N beyond, which the curves shift to the saturation region, confirming that all the samples exhibit the indentation size effect (ISE) nature. Further, the elastic modulus and yield strength values observed reduce with the enhancement of the applied load and Cr inclusions in the Bi-2212 matrix. The experimental findings are also analyzed by Meyer's law, proportional sample resistance model (PSR), modified proportional sample resistance model (MPRS), elastic/plastic deformation model (EPD), and Hays-Kendall (HK) approach. According to the results obtained, the load independent microhardness values calculated by EPD, PSR, and MPSR models are far from the values of the plateau region; however, the HK approach is the most suitable model for the microhardness calculations of the samples prepared in this study. © 2013 Springer Science+Business Media New York.