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Dispersion of oxides, heavy metals, and natural radionuclides in phosphogypsum stockpiles of the phosphate industries in Türkiye

dc.contributor.authorTurhan, Şeref
dc.contributor.authorAltuner, Ergin Murat
dc.contributor.authorAyata, Aytaç
dc.contributor.authorGezer, Ferhat
dc.contributor.authorHançerlioğulları, Aybaba
dc.contributor.authorKurnaz, Aslı
dc.contributor.authorKarataşlı, Muhammet
dc.date.accessioned2026-01-04T21:47:51Z
dc.date.issued2025-03-05
dc.description.abstractAbstract Heavy metal (HM) and naturally occurring radioactive materials (NORM) pollution is continuously increasing due to anthropogenic activities, and it is one of the global problems that pose a threat to human and environmental health. Phosphogypsum (PG), a by-product of phosphate fertilizer (PF) production, is an industrial solid waste produced in large quantities worldwide, and much of it is stockpiled. PG contains enhanced levels of toxic substances such as HMs and NORMs. The first detailed study on the determination of major-minor oxides, HMs, and NORMs contents of PGs collected from waste stockpiles at phosphate fertilizer factories (PFFs) in Türkiye was carried out using energy-dispersive X-ray fluorescence spectrometry to obtain data for the reuse of these wastes and a better characterization of the waste deposit. The major-minor oxides analyzed in the PG samples were ranked as SO3 (53.22%) > CaO (36.84%) > SiO2 (2.08%) > P2O5 (1.21%) > Al2O3 (0.13%) > Fe2O3 (0.11%) according to their average contents. The average contents (mg/kg) of HMs and NORMs analyzed in the PG samples were listed as follows: Fe (744.2) > Ti (102.1) > Zn (59.2) > Mn (28.9) > Ni (18.4) > Cr (15.2) > Co (14.6) > Cu (13.5) > Zr (10.8) > Pb (8.8) > Cd (8.5) > V (7.4) > U (4.9) > Th (4.2). The results revealed that HMs, except Cd and U, were lower than the Earth’s crust averages and maximum soil contaminant levels recommended in the Turkish Regulation on Control of Soil Pollution.
dc.description.urihttps://doi.org/10.1007/s11356-025-36180-2
dc.description.urihttps://pubmed.ncbi.nlm.nih.gov/40042706
dc.description.urihttp://dx.doi.org/10.1007/s11356-025-36180-2
dc.identifier.doi10.1007/s11356-025-36180-2
dc.identifier.eissn1614-7499
dc.identifier.endpage7704
dc.identifier.openairedoi_dedup___::a87485513611b31a5f9b98957dfe4b7d
dc.identifier.pubmed40042706
dc.identifier.scopus2-s2.0-105001494091
dc.identifier.startpage7692
dc.identifier.urihttps://hdl.handle.net/20.500.12597/42538
dc.identifier.volume32
dc.language.isoeng
dc.publisherSpringer Science and Business Media LLC
dc.relation.ispartofEnvironmental Science and Pollution Research
dc.rightsOPEN
dc.subjectRadioisotopes
dc.subjectTurkey
dc.subjectMetals, Heavy
dc.subjectPhosphorus
dc.subjectOxides
dc.subjectFertilizers
dc.subjectCalcium Sulfate
dc.subjectResearch Article
dc.subjectPhosphates
dc.titleDispersion of oxides, heavy metals, and natural radionuclides in phosphogypsum stockpiles of the phosphate industries in Türkiye
dc.typeArticle
dspace.entity.typePublication
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Phosphogypsum (PG), a by-product of phosphate fertilizer (PF) production, is an industrial solid waste produced in large quantities worldwide, and much of it is stockpiled. PG contains enhanced levels of toxic substances such as HMs and NORMs. The first detailed study on the determination of major-minor oxides, HMs, and NORMs contents of PGs collected from waste stockpiles at phosphate fertilizer factories (PFFs) in Türkiye was carried out using energy-dispersive X-ray fluorescence spectrometry to obtain data for the reuse of these wastes and a better characterization of the waste deposit. The major-minor oxides analyzed in the PG samples were ranked as SO<jats:sub>3</jats:sub> (53.22%) &gt; CaO (36.84%) &gt; SiO<jats:sub>2</jats:sub> (2.08%) &gt; P<jats:sub>2</jats:sub>O<jats:sub>5</jats:sub> (1.21%) &gt; Al<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> (0.13%) &gt; Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub> (0.11%) according to their average contents. The average contents (mg/kg) of HMs and NORMs analyzed in the PG samples were listed as follows: Fe (744.2) &gt; Ti (102.1) &gt; Zn (59.2) &gt; Mn (28.9) &gt; Ni (18.4) &gt; Cr (15.2) &gt; Co (14.6) &gt; Cu (13.5) &gt; Zr (10.8) &gt; Pb (8.8) &gt; Cd (8.5) &gt; V (7.4) &gt; U (4.9) &gt; Th (4.2). 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